Product ID:036081-05 NI-332
MSDS Date:01/22/1992
FSC:3439
NIIN:00F030923
MSDS Number: BSMFF

UNION CARBIDE COATING SERVICE CORP

1555 MAIN STREET
INDIANAPOLIS, IN 46224-3283
US

Emergency Phone: 317-240-2186/317-240-2209

Info Phone: 317-240-2186/317-240-2650

Preparer: DELMAR BEIGHT

Cage: UNICA

UNION CARBIDE COATINGS SERVICE CORP

INDIANAPOLIS, IN 48224 US

Telephone: 317-240-2650 OR 800-822-4357

Cage: UNICA

20

RTECS: 9999999WG

NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC,

CAS: 7440-02-0

RTECS: QR5950000

Fraction By Weight: 50-75%

OSHA PEL 1 MG/CUM

ACGIH TLV: 0.05 MG/CUM IC

COBALT

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: 5-20%

OSHA PEL 0.05 MG/CUM

ACGIH TLV: 0.05 MG/CUM

CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: 5-20%

OSHA PEL 1 MG/CUM

ACGIH TLV: 0.5 MG/CUM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TITANIUM (DRY POWDER) (TI)

CAS: 7440-32-6

RTECS: XR1700000

Fraction By Weight: 1-5%

OSHA PEL 5 MG/CUM

ACGIH TLV: 5 MG/CUM

SILICON

CAS: 7440-21-3

RTECS: VW0400000

Fraction By Weight: 1-5%

OSHA PEL 10 MG/CUM

ACGIH TLV: 10 MG/CUM

TUNGSTEN (INSOLUBLE), WOLFRAM

CAS: 7440-33-7

RTECS: YO7175000

Fraction By Weight: 1-5%

OSHA PEL 5 MG/CUM

ACGIH TLV: 5 MG/CUM

MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE

CAS: 7439-98-7

RTECS: QA4680000

Fraction By Weight: 1-5%

OSHA PEL 5 MG/CUM

ACGIH TLV: 5 MG/CUM

ALUMINUM (POWDER)

CAS: 7429-90-5

RTECS: BD0330000

Fraction By Weight: 1-5%

OSHA PEL 15 MG/CUM

ACGIH TLV: 10 MG/CUM (DUST)

Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SKIN: ALLERGIC DERMATITIS/PAPULAR
FORMATION. INGESTION: DEPRESSED CNS. INHALATION: RESPIRATORY TRACT
IRRITANT/DEPRESSED CNS/INTERSTITIAL
PNEUMONITIS/SENSITIZATION/EMPHYSEMA/PULMONARY FIBROTIC DISEASE.
EYES: IRRITANT/CORNEAL DAMAGE/POLYCYTHEMIA/THYROID GLAND
HYPERPLASIA/ALPHA CELL DAMAGE. NICKEL-ECZEMA/NEURODERMATITIS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:SKIN: REDNESS/ULCERS PROGRESSING TO
DRYNESS/SCALING/FEVER/LESION/ITCHING/SORENESS/BURNING SENSATION.
EYE: REDNESS & EXCESS REDNESS OF CONJUNCTIVA. INGESTION:
NAUSEA/ABDOMINAL PAIN/VOMITING/DIARRHEA/BU RNING SENSATION.
INHALATION: CHEST PAIN, VOMITING, DIARRHEA, BURNING SENSATION. ARC
RAYS CAN BURN EYES/SKIN.
Medical Cond Aggravated by Exposure:ASTHMA, INFLAMMATORY OR FIBROTIC
PULMONARY DISEASE, DERMATITIS

First Aid:INGESTION: GIVE AT LEAST 2 GLASSES MILK/WATER. INDUCE
VOMITING UNLESS UNCONSCIOUS. SKIN: WASH THOROUGHLY W/SOAP & WATER.
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY.
EYES: FLUSH THOR OUGHLY W/PLENTY OF WATER. OBTAIN MEDICAL ATTENTION
IN ALL CASES.

Flash Point:NONE
Extinguishing Media:SPECIAL DRY POWDER METAL EXTINGUISHING MATERIAL FOR
METAL FIRES. APPROPRIATE EXTINGUISHER FOR COMBUSTIBLE MATERIALS.
Fire Fighting Procedures:NFPA51 OXYGEN-FUEL GAS SYSTEMS FOR
WELDING/CUTTING & NFPA58 STANDARD FOR THE STORAGE & HANDLING OF
LIQUIFIED PETROLEUM GASES.
Unusual Fire/Explosion Hazard:AIRBORNE DUST PARTICLES/METAL
DUST/ACCUMULATION OF SUCH SHOULD BE TREATED AS EXPLOSIVES.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT TO PROTECT AGAINST
HAZARDS & DISPOSE OF.

Handling and Storage Precautions:WHEN THERMAL SPRAYING, ELECTRICITY CAN
CAUSE FATAL SHOCK. DON'T TOUCH LIVE ELECTRICAL PARTS.
Other Precautions:TAKE PERSONAL AIR SAMPLES & ANALYZE FOR HAZARDOUS
INGREDIENTS/DECOMPOSITION PRODUCTS TO DETERNINE USAGE OF
RESPIRATOR. ALWAYS SPRAY W/ENOUGH VENTILATION. AREA & SPARKS DURING
SPRAYING CAN BE A SOURCES OF IGNITION OF COMBUSTIBLE MATERIALS.

Respiratory Protection:DEPENDS UPON SPECIFIC USE, CONDITION, &
LOCATION. IF THERE IS DUSTINESS, WEAR RESPIRATOR SELECTED BY OSHA.
Ventilation:LOCAL DUST PICK UP & VENTILATION RECOMMENDED
Protective Gloves:REQUIRED WHEN THERMAL SPRAYING
Eye Protection:GOGGLES WHEN DUSTY
Other Protective Equipment:BODY PROTECTION, HELMET, FACE SHIELDS
Supplemental Safety and Health
NOTE TO PHYSICIAN: THE HAZARDS OF THIS MATERIAL ARE MAINLY DUE TO ITS
SENSITIZING & MILD IRRITATING PROPERTIES. THERE IS NO SPECIFIC
ANTIDOTE. TREATMENT OF OVEREXPOSURE SHOULD BE DIRECTED AT THE CONTR
OL OF SYMPTOMS & THE CLINICAL CONDITION. LIQUID DENSITY: HEAVIER
THAN WATER.

Spec Gravity:2.40183
Appearance and Odor:DUSTY YELLOW GRAY POWDER.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:IGNITION SOURCES
Hazardous Decomposition Products:OXIDES, SUB-OXIDES, COMPLEX OXIDES OF
THE MATERIALS OF THIS PRODUCT

Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.